Synthesis
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Zirconyl chloride octahydrate

Synthesis
Product Name
Zirconyl chloride octahydrate
CAS No.
13520-92-8
Chemical Name
Zirconyl chloride octahydrate
Synonyms
ZIRCONIUM OXYCHLORIDE OCTAHYDRATE;ZirconiuM Chloride octahydrate;Zirconium(Ⅳ)oxychloride octahydrate;ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE;ZIRCONIUM(IV) OXYCHLORIDE OCTAHYDRATE;oride Octahydrate;zirconyl(di)chloride;Zirconyl chloride oc;ZirconiumOxychlorideGr;ZIRCONIUM CHLORIDE BASIC
CBNumber
CB9696778
Molecular Formula
Cl2H2O2Zr
Formula Weight
196.14
MOL File
13520-92-8.mol
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Zirconyl chloride octahydrate Property

Melting point:
400°C (dec.)
Boiling point:
210°C
Density 
1.91
storage temp. 
Store at +15°C to +25°C.
solubility 
H2O: soluble
form 
Crystalline Powder
Specific Gravity
1.91
color 
White to light yellow
Odor
Odorless
PH
1 (50g/l, H2O, 20℃)
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
Merck 
14,10184
Exposure limits
ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
Stability:
Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents.
CAS DataBase Reference
13520-92-8(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
34-22-37
Safety Statements 
26-36/37/39-45-27
RIDADR 
UN 3264 8/PG 3
WGK Germany 
1
RTECS 
ZH7250000
TSCA 
Yes
HS Code 
2827 49 90
HazardClass 
8
PackingGroup 
III
Toxicity
LD50 orally in Rabbit: 3500 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
224316
Product name
Zirconyl chloride octahydrate
Purity
reagent grade, 98%
Packaging
5g
Price
$55
Updated
2024/03/01
Sigma-Aldrich
Product number
224316
Product name
Zirconyl chloride octahydrate
Purity
reagent grade, 98%
Packaging
100g
Price
$154
Updated
2024/03/01
Sigma-Aldrich
Product number
1.08917
Product name
Zirconium(IV) oxide chloride octahydrate
Purity
for analysis EMSURE?
Packaging
100g
Price
$178
Updated
2024/03/01
Sigma-Aldrich
Product number
224316
Product name
Zirconyl chloride octahydrate
Purity
reagent grade, 98%
Packaging
500g
Price
$455
Updated
2024/03/01
Alfa Aesar
Product number
A12342
Product name
Zirconium dichloride oxide octahydrate
Purity
98%
Packaging
100g
Price
$64.2
Updated
2023/06/20
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Zirconyl chloride octahydrate Chemical Properties,Usage,Production

Synthesis

Zircon is melted with caustic soda, rinsed, desiliconized, and then reacted with sulfuric acid, and then ammonia water is added to obtain zirconium hydroxide precipitate. Finished zirconium oxychloride.

Chemical Properties

solid

Uses

Zirconium dichloride oxide is utilized as a precursor to prepare other zirconium compounds. It is employed in acid dyes, pigment toners and antiperspirants. It finds application as a rubber additive and a fiber treatment agent. It is also used in paint drying, refractories, ceramics and glaze.

General Description

This product is used as a potential green catalyst.

Purification Methods

Recrystallise the chloride several times from water [Ferragina et al. J Chem Soc, Dalton Trans 265 1986]. Recrystallisation from 8M HCl gives the octahydrate as white needles on concentrating. It is also formed by hydrolysing ZrCl4 with water. After one recrystallisation from H2O, 99+% grade zirconyl chloride had Ag, Al, As, Cd, Cu, Hf, Mg, Na, Sc and V at 20, 1.8, 0.6, 0.6, 0.4, 8.4, 0.4, 2.4, 80 and 3 ppm, respectively. (See above.) METAL-ORGANIC COMPOUNDS This section contains metal-organic compounds as well as ammonium and metal salts of organic acids. (For Introduction see p 445.)

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Zirconyl chloride octahydrate Suppliers

HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10658
Advantage
60
Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
52927
Advantage
58
Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57511
Advantage
58
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View Lastest Price from Zirconyl chloride octahydrate manufacturers

Henan Fengda Chemical Co., Ltd
Product
Zirconyl chloride octahydrate 13520-92-8
Price
US $8.00-1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-03
Hebei Guanlang Biotechnology Co,.LTD
Product
Zirconyl chloride octahydrate 13520-92-8
Price
US $1.60/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000kg
Release date
2021-07-09
Career Henan Chemical Co
Product
Zirconyl chloride octahydrate 13520-92-8
Price
US $1.00/KG
Min. Order
1KG
Purity
995
Supply Ability
25kg
Release date
2019-07-12

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